Сульфид кадмия

144.48

145.875

215-147-8

0404

2570

Yellow-orange hexagonal crystals|Light-yellow or orange-colored cubic or hexagonal crystals.|Yellow or brown powder|Dimorphic, existing in the sphalerite (cubic) and wurtzite (hexagonal) crystal structures.

2830909000

32.1

0.64570

LIGHT YELLOW OR ORANGE CRYSTALS OR YELLOW-TO-BROWN POWDER.

4.8 g/cm³

980 °C (sublm)

4℃

INDEX OF REFRACTION: 2.506; 2.529

H2O: Insoluble ;soluble in acid, very slightly soluble in ammonium hydroxide.

2-8°C

Oral-rat LD50: 7080 mg/kg; Oral-Mouse LD50: 1166 mg/kg

Thermal decomposition releases toxic sulfur oxides, containing cadmium fumes

Can be polished like a metal. It is an n-type semiconductor.|beta-Cadmium sulfide can be transformed to alpha-cadmium sulfide by heating at 750 °C in a sulfur atmosphere.|Sublimes at 980 °C|Oxidized to the sulfate, basic sulfate and eventually the oxide on heating in air to 700 °C, especially in the presence of moisture.|log Ksp = -14.36 at 25 °C and 1 atm. (This value was determined for long equilibrium times and is as much as 2 orders of magnitude for published values for fresh precipitates.)

III

6.1

UN 3077 9/PG 3

3

45-22-48/23/25-53-62-63-68-50/53-67-65-48/20/22-38-11

53-45-61-60-62-36/37-16

EV3150000

T,N,F

The warehouse is low-temperature, ventilated and dry

P201, P202, P260, P264, P270, P273, P281, P301+P312, P308+P313, P314, P330, P405, P501

H302

Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number D006, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste.|Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number D006, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste. /Cadmium/|SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

The reaction between iodine monochloride & cadium sulfide ... is vigorous.

National Toxicology Program. Eleventh Report on Carcinogens (2005). The Report on Carcinogens is an informational scientific and public health document that identifies and discusses substances (including agents, mixtures, or exposure circumstances) that may pose a carcinogenic hazard to human health. Cadmium and Cadmium Compounds are listed as known to be human carcinogens. /Cadmium and Cadmium Compounds/[Available from, as of July 31, 2009: http://ntp.niehs.nih.gov/ntp/roc/eleventh/profiles/s028cadm.pdf]

Combustible. Gives off irritating or toxic fumes (or gases) in a fire.

|Danger|H302: Harmful if swallowed [Warning Acute toxicity, oral]|P201, P202, P260, P264, P270, P273, P281, P301+P312, P308+P313, P314, P330, P405, and P501|H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]|P201, P202, P260, P264, P270, P273, P281, P301+P312, P308+P313, P314, P330, P391, P405, and P501|Aggregated GHS information provided by 259 companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H341: Suspected of causing genetic defects [Warning Germ cell mutagenicity]|P201, P202, P260, P264, P270, P281, P307+P311, P308+P313, P314, P321, P405, and P501|P201, P202, P260, P264, P270, P280, P281, P301+P312, P302+P352, P305+P351+P338, P308+P313, P309+P311, P314, P321, P330, P332+P313, P337+P313, P362, P405, and P501

If material on fire or involved in fire: Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog. Use "alcohol" foam, dry chemical or carbon dioxide. /Cadmium compounds, NOS/

SRP: Contaminated protective clothing should be segregated in such a manner so that there is no direct personal contact by personnel who handle, dispose, or clean the clothing. Quality assurance to ascertain the completeness of the cleaning procedures should be implemented before the decontaminated protective clothing is returned for reuse by the workers. All contaminated clothing should not be taken home at end of shift, but should remain at employee's place of work for cleaning.

/GUIDE 154: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE)/ First Aid: Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. /Cadmium compound/|/GUIDE 154: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE)/ Spill or Leak: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. /Cadmium compound/|/GUIDE 154: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE)/ Fire: Small fires: Dry chemical, CO2 or water spray. Large fires: Dry chemical, CO2, alcohol-resistant foam or water spray. Move containers from fire area if you can do it without risk. Dike fire control water for later disposal; do not scatter the material. Fire involving tanks or car/trailer loads: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. /Cadmium compound/|/GUIDE 154: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE)/ Evacuation: ... Fire: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. /Cadmium compound/|For more DOT Emergency Guidelines (Complete) data for CADMIUM SULFIDE (8 total), please visit the HSDB record page.

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.

Provision to contain effluent from fire extinguishing. Separated from strong oxidants, strong acids and food and feedstuffs. Store in an area without drain or sewer access.

A harmful concentration of airborne particles can be reached quickly when dispersed, especially if powdered.

May cause mechanical irritation to the eyes.

The substance may have effects on the kidneys, bones and respiratory tract. This may result in kidney impairment, osteoporosis (bone weakness) and chronic inflammation of the respiratory tract. This substance is carcinogenic to humans.

NO open flames.

PREVENT DISPERSION OF DUST! AVOID ALL CONTACT!

Use local exhaust or breathing protection.

Protective gloves.

Wear safety goggles or eye protection in combination with breathing protection if powder.

Listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Cadmium sulfide is included on this list.

The major hazards encountered in the use and handling of cadmium sulfide stem from its toxicologic properties. Toxic primarily by ingestion and inhalation, exposure to this yellow, orange, red, or brown crystalline substance may occur from its use as a pigment for coloring glass, soaps, textiles, paper, rubber, inks, ceramic glazes, fireworks, and epoxy resins. Effects from exposure may include headache, shortness of breath, chest pain, kidney damage, liver damage, emphysema, chronic bronchitis, and pulmonary edema (possibly resulting in death). Processes and operations which may release cadmium fumes or dust should be enclosed and fitted with exhaust ventilation. In activities where over-exposure is possible, workers should wear a high efficiency particulate filter respirator or self-contained breathing apparatus. Protective clothing also should be worn. Preferably this should include disposable one piece suits (close-fitting at the ankles and wrists), gloves, hair covering, and overshoes. These should be removed before leaving work. If contact should occur, immediately wash contaminated skin with large amounts of water. Do not eat, smoke, or drink in work areas. Cadmium sulfide presents only a moderate fire hazard (when in the form of dust) if exposed to heat, flame, or by chemical reaction with oxidizing agents, metals, hydrogen azide, zinc, selenium, or tellurium. Wear a self-contained breathing apparatus when fighting such fires. Cadmium sulfide should be stored in cool, well-ventilated areas, out of direct rays of sun, and away from combustibles and other fire hazards. Should hazardous concentrations of cadmium sulfide are accidentally released, remove all ignition sources, ventilate the area, and collect the released material in closed containers for disposal. Before implementing land disposal of waste cadmium sulfide, consult environmental regulatory agencies for guidance.

D006; A waste containing cadmium may or may not be characterized as a hazardous waste following testing by the Toxicity Characteristic Leaching Procedure as prescribed by the Resource Conservation and Recovery Act (RCRA) regulations. /Cadmium/

D006; A solid waste containing cadmium may or may not become characterized as a hazardous waste when subjected to the Toxicity Characteristic Leaching Procedure listed in 40 CFR 261.24, and if so characterized, must be managed as a hazardous waste. /Cadmium/